Thermodynamic properties of LiCl solutions in N-methylacetamide at 308.15–328.15 K

Enthalpies of dissolution of crystalline LiCl and enthalpies of dilution of LiCl solutions in N -methylacetamide (NMA) with electrolyte concentrations no greater than 0.32 m are measured on an isoperibolic calorimeter at 308.15, 318.15, and 328.5 K. Standard enthalpies of the dissolution of LiCl in...

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Bibliographic Details
Published inRussian Journal of Physical Chemistry A Vol. 91; no. 12; pp. 2293 - 2301
Main Authors Manin, N. G., Kolker, A. M.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.12.2017
Springer Nature B.V
Subjects
Chemical Thermodynamics and Thermochemistry
Chemistry
Chemistry and Materials Science
Dilution
Dissolution
Enthalpy
Mathematical analysis
Physical Chemistry
Thermodynamic properties
methylacetamide
LiCl
enthalpy of dissolution and dilution
thermochemistry
relative partial enthalpy and heat capacity
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Summary:Enthalpies of dissolution of crystalline LiCl and enthalpies of dilution of LiCl solutions in N -methylacetamide (NMA) with electrolyte concentrations no greater than 0.32 m are measured on an isoperibolic calorimeter at 308.15, 318.15, and 328.5 K. Standard enthalpies of the dissolution of LiCl in NMA are calculated at different temperatures. The thermodynamic properties of the solution and its components are calculated and analyzed in the investigated range of concentrations and temperatures.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024417120184