Pinecone biomass‐derived activated carbon: the potential electrode material for the development of symmetric and asymmetric supercapacitors

• Published in: International journal of energy research Vol. 44; no. 11; pp. 8591 - 8605
• Main Authors: Rajesh, Murugesan, Manikandan, Ramu, Park, Seungil, Kim, Byung Chul, Cho, Won‐Je, Yu, Kook Hyun, Raj, C. Justin
• Format: Journal Article
• Language: English
• Published: Chichester, UK John Wiley & Sons, Inc 01.09.2020; Hindawi Limited
• Subjects: Activated carbon; asymmetric supercapacitor; Asymmetry; Biomass; biomass activated carbon; Capacitance; Carbon; Chemical synthesis; Computer architecture; Electric potential; Electrochemistry; Electrode materials; Electrodes; Electrolytes; Fabrication; Feasibility studies; impedance spectroscopy; Nanostructure; PEDOT; Pyrolysis; Sodium sulfate; specific energy; Stability; Sulfuric acid; Sulphuric acid; Supercapacitors; Voltage
• ISSN: 0363-907X; 1099-114X
• DOI: 10.1002/er.5548

Summary Activated carbon, from biomass (pinecone), was synthesized by conventional pyrolysis/chemical activation process and utilized for the fabrication of supercapacitor electrodes. The pinecone‐activated carbon synthesized with 1:4 ratio of KOH (PAC4) showed an increase in surface area and pore density with a considerable amount of oxygen functionalities on the surface. Moreover, PAC4, as supercapacitor electrode, exhibited excellent electrochemical performances with specific capacitance value ∼185 Fg−1 in 1 M H2SO4, which is higher than that of nonactivated pinecone carbon and 1:2 ratio KOH‐based activated carbon (PAC2) (∼144 Fg−1). The systematic studies were performed to design various forms of devices (symmetric and asymmetric) to investigate the effect of device architecture and operating voltage on the performance and stability of the supercapacitors. The symmetric supercapacitor, designed utilizing PAC4 in H2SO4 electrolyte, exhibited a maximum device‐specific capacitance of 43 Fg−1 with comparable specific energy/power and excellent stability (∼96% after 10 000 cycles). Moreover, a symmetric supercapacitor was specially designed using PAC4, as a positive electrode, and PAC2, as a negative electrode, under their electrolytic ion affinity, and which operates in aqueous Na2SO4 electrolyte for a wide cell voltage (1.8 V) and showed excellent supercapacitance performances. Also, a device was assembled with poly(3,4‐ethylene dioxythiophene) (PEDOT) nanostructure, as positive electrode, and PAC4, as a negative electrode, to evaluate the feasibility of designing a hybrid supercapacitor, using polymeric nanostructure, as an electrode material along with biomass‐activated carbon electrode. Activated carbons were synthesized from biomass using two different mass ratio of activation agent and the activated carbon showed excellent electrochemical performances. For the first time, an symmetric supercapacitor was designed, utilizing two different surface‐natured activated carbon electrodes, and a hybrid supercapacitor was designed using conducting polymer PEDOT and biomass‐activated carbon electrode.