Micro‐hardness and gamma‐ray attenuation properties of lead iron phosphate glasses

• Published in: Journal of materials science. Materials in electronics Vol. 32; no. 10; pp. 13906 - 13916
• Main Authors: Al-Buriahi, M. S., Eke, Canel, Alomairy, Sultan, Mutuwong, Chalermpon, Sfina, Noureddine
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.05.2021; Springer Nature B.V
• Subjects: Attenuation; Barite; Characterization and Evaluation of Materials; Chemistry and Materials Science; Concrete; Elastic properties; Glass; Investigations; Iron; Materials Science; Microhardness; Optical and Electronic Materials; Phosphorus pentoxide; Physics; Radiation; Radiation shielding; Radioactive wastes; Science education; Simulation
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-021-05966-8

For safe immobilization of nuclear waste, lead-iron phosphate glasses are promising as high-level commercial and defense materials. In this research article, the compositional, elastic, and gamma shielding properties of the glasses containing (80 − x)P 2 O 5 – xFe 2 O 3 –20PbO with x = 20, 25, 30, 35 mol% were reported. The compositional and elastic parameters including the micro-hardness of the investigated glass samples were obtained based on Makishima-Mackenzie’s theory (MM-theory) and R model. We found that the deviation between these two methods decreased as Fe 2 O 3 concentrations increased from 20 to 35 mol %. Additionally, γ-ray attenuation properties of the P 2 O 5 – Fe 2 O 3 –PbO glass system were evaluated using Geant4 simulation toolkit. The simulation results were compared with the theoretical ones extracted from Py-MLBUF software. The obtained results reveal that the MACs of the glasses vary from 0.030 to 40.014 cm 2 /g for PFP-A, from 0.031 to 41.502 cm 2 /g for PFP-B, 0.031 to 43 cm 2 /g for PFP-C and from 0.031 to 44.400 cm 2 /g for PFP-D. Maximum Z eff values of present glasses are obtained at 0.10 MeV whereas minimum Z eff values are obtained at 1.5 MeV. Finally, the fundamental γ-ray attenuation properties of the P 2 O 5 – Fe 2 O 3 –PbO glass system are found to be comparable with those of traditional and commercial radiation shields such as RS-253-G18 and RS-360 commercial glasses, ordinary concrete, barite concrete and TBZP10 from scientific literature. The results indicated that MFPs of the investigated glasses are lower than those of RS-360 glass, but they are higher than those of barite concrete and TBZP10.