Kinetic study of chromium(VI) facilitated transport through a bulk liquid membrane using tri- n-butyl phosphate as carrier

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 150; no. 1; pp. 83 - 89
• Main Authors: Zhang, Weidong, Liu, Junteng, Ren, Zhongqi, Wang, Shuguang, Du, Changshun, Ma, Jingnan
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier B.V 15.07.2009; Elsevier
• Subjects: Applied sciences; Bulk liquid membrane; Chemical engineering; Cr(VI); Exact sciences and technology; Heat and mass transfer. Packings, plates; Kinetic model; Tri- n-butyl phosphate; Bulk liquid membrane; Kinetic model; Cr(VI); Tri- n-butyl phosphate; Stripping; Liquid membrane; Modeling; Tri-n-butyl phosphate; Mass transfer; Operating conditions; Transport process; First order; Kinetics; Facilitated transport
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2008.12.009

The facilitated transport of Cr(VI) through a bulk liquid membrane (BLM) is investigated, using the commercially available solvent tri- n-butyl phosphate (TBP) as mobile carrier. The influences of the carrier concentration in the liquid membrane phase, the HCl concentration of the feed phase, and the stripping concentration on the mass transfer process are studied. The transport rate of Cr(VI) increases with increasing the TBP concentration and HCl concentration. The increasing of the stripping concentration improves the stripping process until a plateau is reached. A kinetic model is used to describe the Cr(VI) transport behavior, assuming that it obeys the kinetic laws of two consecutive irreversible first-order reactions. The experimental data fits reasonable well with the derived model. The analysis of the accumulation of Cr(VI) in the liquid membrane phase and the discussion of the rate-controlling step under different experimental conditions are carried out. The magnitude of the value of k e and k s is found to be 10 −4–10 −5 s −1, and is well in agreement with other studies.