Microscopic model of the optical absorption of carbon nanotubes functionalized with molecular spiropyran photoswitches

• Published in: Physical review letters Vol. 106; no. 9; p. 097401
• Main Authors: Malic, E, Weber, C, Richter, M, Atalla, V, Klamroth, T, Saalfrank, P, Reich, S, Knorr, A
• Format: Journal Article
• Language: English
• Published: United States 01.03.2011
• ISSN: 1079-7114
• DOI: 10.1103/PhysRevLett.106.097401

The adsorption of molecules to the surface of carbon nanostructures opens a new field of hybrid systems with distinct and controllable properties. We present a microscopic study of the optical absorption in carbon nanotubes functionalized with molecular spiropyran photoswitches. The switching process induces a change in the dipole moment leading to a significant coupling to the charge carriers in the nanotube. As a result, the absorption spectra of functionalized tubes reveal a considerable redshift of transition energies depending on the switching state of the spiropyran molecule. Our results suggest that carbon nanotubes are excellent substrates for the optical readout of spiropyran-based molecular switches. The gained insights can be applied to other noncovalently functionalized one-dimensional nanostructures in an externally induced dipole field.