Study of second-order nonlinear hyperpolarisability of all-trans-β-carotene in solutions by linear spectroscopic technique

• Published in: Chinese physics B Vol. 19; no. 6; pp. 362 - 366
• Main Author: 房文汇 门志伟 孙成林 曲冠男 杨光 里佐威 高淑琴 陆国会
• Format: Journal Article
• Language: English
• Published: IOP Publishing 01.06.2010
• ISSN: 1674-1056; 2058-3834
• DOI: 10.1088/1674-1056/19/6/064213

This paper demonstrates the second-order nonlinear hyperpolarisability γ of all-trans-β-carotene in different solvents by linear spectroscopic technique that is based on resonance Raman scattering and UV-VIS （Ultraviolet-visible） absorption spectroscopy. Owing to the two-level model well describing the link that exists between the resonance Raman scattering and stimulated Raman scattering, the stimulated Raman polarisability αR can be calculated through the two-photon resonance system. The value of γ of all-trans-β-carotene in carbon bisulfide solution is 6.435×10^-33 esu （1 esu of resistance = 8.98755×10^11Ω） that is close to the true value, because the solution of all-trans-β-carotene in carbon bisulfide satisfies the rigid resonance Raman scattering condition. This method is expected to be worthy of applications to measure the second-order nonlinear hyperpolaxisability of a conjugate organic molecule.