Rotational oscillations of a molecular chain with quadrupolar interaction
Molecular chains with rotational degree of freedom in the plane of an adsorbing surface and quadrupolar interaction between linear molecules are investigated theoretically. It is found that alternation ordering of the molecules is preferable. Equations of rotational movement are derived and solved f...
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Published in | Physica status solidi. C Vol. 1; no. 11; pp. 3052 - 3056 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Berlin
WILEY-VCH Verlag
01.11.2004
WILEY‐VCH Verlag |
Subjects | |
Online Access | Get full text |
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Summary: | Molecular chains with rotational degree of freedom in the plane of an adsorbing surface and quadrupolar interaction between linear molecules are investigated theoretically. It is found that alternation ordering of the molecules is preferable. Equations of rotational movement are derived and solved for linear oscillations. It is shown that dispersion relation has two optic branches of rotational excitations. The normal coordinates are found to be strongly dependent on dispersion. In the long wave limit normal coordinates are symmetric and antisymmetric. The heat capacity of the molecular chain is found at low temperature. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) |
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Bibliography: | ArticleID:PSSC200405308 ark:/67375/WNG-MK8DBHR6-N istex:338C9F72A7609BBFC41F60449A0B260AE82BA859 Phone: +38 0572 300 390, Fax: +38 0572 322 370 SourceType-Scholarly Journals-2 ObjectType-Feature-2 ObjectType-Conference Paper-1 content type line 23 SourceType-Conference Papers & Proceedings-1 ObjectType-Article-3 |
ISSN: | 1610-1634 1610-1642 |
DOI: | 10.1002/pssc.200405308 |