The structure of bartemidiolide, a clerodane-type diterpene from Baccharis artemisioides

The structure and stereochemistry of a clerodane-type diterpene from Baccharis artemisioides which we have named bartemidiolide, 15,16-3α,4α-diepoxy- trans-cleroda-13(16),14-diene-20,12 S-19,2β-diolide, have been determined by X-ray crystallographic analysis and spectroscopic data.

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Bibliographic Details
Published inPhytochemistry (Oxford) Vol. 27; no. 2; pp. 489 - 491
Main Authors Tonn, Carlos E., Giordano, Oscar S., Bessalle, Roberto, Frolow, Felix, Lavie, David
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier Ltd 1988
Elsevier
Subjects
Analytical, structural and metabolic biochemistry
Baccharis
Baccharis artemisioides
bartemidiolide
Biological and medical sciences
chemical constituents of plants
clerodane
Compositae
diterpene
Fundamental and applied biological sciences. Psychology
Other biological molecules
stereochemistry
structure
Terpenes, steroids. Hormones
X-ray analysis
X-ray analysis
clerodane
bartemidiolide
Baccharis artemisioides
Compositae
diterpene
Vegetals
Molecular structure
Dicotyledones
Angiospermae
Diterpene
Spermatophyta
Stereochemistry
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Summary:The structure and stereochemistry of a clerodane-type diterpene from Baccharis artemisioides which we have named bartemidiolide, 15,16-3α,4α-diepoxy- trans-cleroda-13(16),14-diene-20,12 S-19,2β-diolide, have been determined by X-ray crystallographic analysis and spectroscopic data.
ISSN:0031-9422
1873-3700
DOI:10.1016/0031-9422(88)83127-3