Interfacing Si‐Based Electrodes: Impact of Liquid Electrolyte and Its Components

• Published in: Advanced materials interfaces Vol. 9; no. 8
• Main Authors: Wölke, Christian, Sadeghi, Bahareh A., Eshetu, Gebrekidan G., Figgemeier, Egbert, Winter, Martin, Cekic‐Laskovic, Isidora
• Format: Journal Article
• Language: English
• Published: Weinheim John Wiley & Sons, Inc 01.03.2022
• Subjects: Electrode materials; Electrodes; Electrolytes; Energy storage; Flux density; functional additives; Lithium; lithium salt; Lithium-ion batteries; Silicon; silicon electrode
• ISSN: 2196-7350; 2196-7350
• DOI: 10.1002/admi.202101898

As the demand for mobile energy storage devices has steadily increased during the past decades due to the rising popularity of portable electronics as well as the continued implementation of electromobility, energy density has become a crucial metric in the development of modern batteries. It was realized early on that the successful utilization of silicon as negative electrode material in lithium‐ion batteries would be a quantum leap in improving achievable energy densities due to the roughly ten‐fold increase in specific capacity compared to the state‐of‐the‐art graphite material. However, being an alloying type material rather than an intercalation/insertion type, silicon poses numerous obstacles that need to be overcome for its successful implementation as a negative electrode material with the most prominent one being its extreme volume changes on (de‐)lithiation. While, as of today, a plethora of different types of Si‐based electrodes have been reported, a universally common feature is the interface between Si‐based electrode and electrolyte. This review focuses on the knowledge gained thus far on the impact of different liquid electrolyte components/formulations on the interfaces and interphases encountered at Si‐based electrodes. Silicon‐based electrodes are in the focus of numerous research endeavors aiming at increasing the energy density of lithium‐ion batteries. Overcoming the imposed challenges around silicon as negative electrode, addresses tailoring of electrolyte formulation(s). This work highlights wide variety of different compounds used as electrolyte solvents/co‐solvents, conducting salts and additives and summarizes their impact on the interphases formed on silicon‐based electrodes.