Preparation and Structure Determination of a Stable cis-Bis-σ-homobenzene Derivative
By cyclopropanation of tetramethyl[2.2]paracyclophane 9 the tetramethylene adduct 10 has been prepared. This hydrocarbon is the first stable cis‐bis‐σ‐homobenzene for which a structure has been determined by X‐ray diffraction. By cyclopropanation of a [2.2]paracyclophane a stable cis‐bis‐σ‐homobenze...
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Published in | European Journal of Organic Chemistry Vol. 2010; no. 21; pp. 4046 - 4048 |
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Main Authors | , , |
Format | Book Review Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
01.07.2010
WILEY‐VCH Verlag Wiley Wiley-VCH |
Subjects | |
Online Access | Get full text |
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Summary: | By cyclopropanation of tetramethyl[2.2]paracyclophane 9 the tetramethylene adduct 10 has been prepared. This hydrocarbon is the first stable cis‐bis‐σ‐homobenzene for which a structure has been determined by X‐ray diffraction.
By cyclopropanation of a [2.2]paracyclophane a stable cis‐bis‐σ‐homobenzene derivative was prepared. The X‐ray structure of this hydrocarbon is the first for this class of compounds. |
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Bibliography: | ark:/67375/WNG-00L5LZVJ-0 istex:30E8B14742F4CC0AD58D3A43891456DDD0A5AA7D Cyclophanes, LXV. Part LXIV: Ref.1 ArticleID:EJOC201000114 1 Cyclophanes, LXV. Part LXIV: Ref. |
ISSN: | 1434-193X 1099-0690 |
DOI: | 10.1002/ejoc.201000114 |