Phosphate-modified cobalt silicate hydroxide with improved oxygen evolution reaction

• Published in: Journal of colloid and interface science Vol. 648; pp. 251 - 258
• Main Authors: Ding, Chongtao, Yu, Yao, Wang, Yu, Mu, Yang, Dong, Xueying, Meng, Changgong, Huang, Chi, Zhang, Yifu
• Format: Journal Article
• Language: English
• Published: United States Elsevier Inc 15.10.2023
• Subjects: Co3(Si2O5)2(OH)2 hollow spheres; Electrocatalyst; Oxygen evolution reaction; Phosphorization; Surface decoration; Electrocatalyst; Oxygen evolution reaction; Phosphorization; Surface decoration; Co3(Si2O5)2(OH)2 hollow spheres; Co(SiO)(OH) hollow spheres
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2023.06.007

[Display omitted] Oxygen Evolution Reaction (OER) has gained significant attention due to its crucial role in renewable energy systems. The quest for efficient and low-cost OER catalysts remains a challenge of significant interest and importance. In this work, phosphate-incorporated cobalt silicate hydroxide (denoted as CoSi-P) is reported as a potential electrocatalyst for OER. The researchers first synthesized hollow spheres of cobalt silicate hydroxide Co3(Si2O5)2(OH)2 (denoted as CoSi) using SiO2 spheres as a template through a facile hydrothermal method. Phosphate (PO43−) was then introduced to layered CoSi, leading to the reconstruction of the hollow spheres into sheet-like architectures. As expected, the resulting CoSi-P electrocatalyst demonstrated low overpotential (309 mV at 10 mA·cm−2), large electrochemical active surface area (ECSA), and low Tafel slope. These parameters outperform CoSi hollow spheres and cobaltous phosphate (denoted as CoPO). Moreover, the catalytic performance achieved at 10 mA cm−2 is comparable or even better than that of most transition metal silicates/oxides/hydroxides. The findings indicate that the incorporation of phosphate into the structure of CoSi can enhance its OER performance. This study not only provides a non-noble metal catalyst CoSi-P but also demonstrates that the incorporation of phosphates into transition metal silicates (TMSs) offers a promising strategy for the design of robust, high-efficiency, and low-cost OER catalysts.