Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster

A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis,...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 51; no. 73; pp. 13890 - 13893
Main Authors Lichtenberg, C, Viciu, L, Vogt, M, Rodríguez-Lugo, R E, Adelhardt, M, Sutter, J, Khusniyarov, M M, Meyer, K, de Bruin, B, Bill, E, Grützmacher, H
Format Journal Article
LanguageEnglish
Published England 21.09.2015
Subjects
Clusters
Electronic structure
Iron
Magnetic permeability
Metathesis
Mossbauer spectroscopy
Single crystals
X-ray diffraction
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Summary:A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc04908c