The g-C3N4-TiO2 nanocomposite for non-volatile memory and artificial synaptic device applications

• Published in: Journal of alloys and compounds Vol. 962; p. 171024
• Main Authors: Patil, S.L., Pawar, O.Y., Patil, H.S., Sutar, S.S., Kamble, G.U., Kim, Deok-kee, Kim, Jin Hyeok, Kim, Tae Geun, Kamat, R.K., Dongale, T.D., Tarwal, N.L.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 05.11.2023
• Subjects: Ex-Situ method; g-C3N4-TiO2 nanocomposite; Memristor; Resistive switching; Synaptic learning; Time series analysis; Memristor; Synaptic learning; g-C3N4-TiO2 nanocomposite; Ex-Situ method; Time series analysis; Resistive switching
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2023.171024

Recently, 2D layered materials like graphitic carbon nitride (g-C3N4) are gaining significant attention due to their excellent structural and electronic properties. Metal oxide and g-C3N4 composite can enhance chemical and electronic properties which can ultimately enhance device performance. Given this, we report the synthesis of g-C3N4–TiO2 nanocomposite by the ex-situ (solid state reaction) method for resistive switching (RS) applications. Initially, the TiO2 nanoparticles (NPs) were optimized by using annealing them at different temperatures and composited with the g-C3N4. The devices fabricated using g-C3N4–TiO2 nanocomposite shows good RS properties at very low SET and RESET voltages (< 0.5 V), similar to the biological voltage scale. The distribution of switching voltages of all devices was studied using the cumulative probability and Weibull distribution techniques. Moreover, switching voltages were modeled and predicted using the statistical time series analysis method. All fabricated devices demonstrated the double-valued charge flux characteristics, suggesting the presence of a non-ideal memristor effect. The optimized g-C3N4-TiO2 (TiO2 NPs annealed at 450 °C) device shows good endurance and retention memory properties. Moreover, the optimized g-C3N4-TiO2 device can mimic the various bio-synaptic properties such as potentiation-depression, excitatory postsynaptic current, and paired-pulse facilitation. The charge transport results reveal that Ohmic and Child's square law dominated the conduction of the device. Based on electrical and charge transport results, a plausible filamentary RS effect is presented. This study suggested that the g-C3N4-TiO2 is beneficial for both memory and neuromorphic computing applications. •Ex-situ synthesis of g-C3N4-TiO2 nanocomposite for resistive switching applications.•Demonstration of biological voltage scale SET and RESET voltages (< ± 0.5 V).•Switching voltages modeled using statistical time series analysis technique.•The g-C3N4-TiO2 nanocomposite shows excellent non-volatile memory properties.•The g-C3N4-TiO2 nanocomposite mimics various biological synaptic properties.