Melt processing of ethylene–vinyl acetate/banana starch/Cloisite 20A organoclay nanocomposite films: structural, thermal and composting behavior

• Published in: Iranian polymer journal Vol. 29; no. 8; pp. 723 - 733
• Main Authors: García-Muñoz, Miguel A., Valera-Zaragoza, Mario, Aparicio-Saguilán, Alejandro, Peña-Rico, Miguel A., Juarez-Arellano, Erick A., Aguirre-Cruz, Andrés, Ramírez-Vargas, Eduardo, Sánchez-Valdes, Saúl
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01.08.2020; Springer Nature B.V
• Subjects: Ceramics; Chemistry; Chemistry and Materials Science; Composites; Composting; Copolymers; Damage; Differential scanning calorimetry; Emission analysis; Ethylene vinyl acetates; Extrusion; Fatty acids; Field emission microscopy; Glass; Homogeneity; Mechanical properties; Microorganisms; Nanocomposites; Natural Materials; Natural polymers; Original Research; Polymer Sciences; Scanning electron microscopy; Soil testing; Thermogravimetric analysis; Composting; Ethylene vinyl acetate; Nanocomposites; Banana starch; Organoclay
• ISSN: 1026-1265; 1735-5265
• DOI: 10.1007/s13726-020-00835-3

This work shows the preparation of ethylene vinyl acetate copolymer/banana starch/Cloisite 20A organoclay (EVA/starch/C20A) nanocomposites by melt processing. Wide angle X-ray diffraction (WAXD), field emission scanning electron microscopy (FE-SEM), differential scanning calorimetry and thermogravimetric analysis were used to characterize the obtained nanocomposites. Mechanical properties were also determined. In addition, the performance of the nanocomposite films under composting was preliminarily studied; it was conducted using the soil burial test method. Despite knowing that the starch is difficult to process by extrusion, nanocomposite films with high homogeneity were obtained. In this case, C20A organoclay acts as an effective surfactant to make the starch natural polymer compatible with the EVA synthetic polymer. The good compatibility between EVA, starch and C20A clay was also deduced by the formation of intercalated and intercalated-exfoliated structures determined by WAXD and FE-SEM. Physical evidence of the damage in EVA/starch/C20A nanocomposite films after the composting test was observed. It is worth noting that despite the absence of starch, the EVA/C20A nanocomposite film, used as a control, also showed surface damage. This behavior is related to the organic modifier linked to clay C20A, which contains molecules derived from fatty acids that can be used as a food source for microorganisms.