Halogen bonding between metal centers and halocarbons

Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk2)2] (X = Cl, Br). The HI2C-Iη(1)(Pt) halogen bonding and the bifurcated HI2C-Iη(2)(Pt-Cl) halogen bonding - the latter undergoes the thermally induced reversible HI2C-I∙∙∙η(2)(Pt-Cl) ⇄ HI2C-I∙∙∙η(1...

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Published inChemical communications (Cambridge, England) Vol. 52; no. 32; pp. 5565 - 5568
Main Authors Ivanov, Daniil M, Novikov, Alexander S, Ananyev, Ivan V, Kirina, Yulia V, Kukushkin, Vadim Yu
Format Journal Article
LanguageEnglish
Published England 25.04.2016
Subjects
Bifurcation theory
Bonding
Halocarbons
Halogens
Transformations
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Summary:Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk2)2] (X = Cl, Br). The HI2C-Iη(1)(Pt) halogen bonding and the bifurcated HI2C-Iη(2)(Pt-Cl) halogen bonding - the latter undergoes the thermally induced reversible HI2C-I∙∙∙η(2)(Pt-Cl) ⇄ HI2C-I∙∙∙η(1)(Pt) transformation - were observed and confirmed theoretically.
Bibliography:ObjectType-Article-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc01107a