Synthesis and structure of Zr(iv)- and Ce(iv)-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

Two new MOFs denoted as M-CAU-24 (M = Zr, Ce) based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H TCPB) were obtained under mild reaction conditions within 15 min. The MOFs with composition [M (μ -O) (μ -OH) (OH) (H O) (TCPB) ] crystallise in the scu topology, a connectivity hitherto unreported for...

Full description

Saved in:
Bibliographic Details
Published inDalton transactions : an international journal of inorganic chemistry Vol. 45; no. 47; pp. 18822 - 18826
Main Authors Lammert, M, Reinsch, H, Murray, C A, Wharmby, M T, Terraschke, H, Stock, N
Format Journal Article
LanguageEnglish
Published England 21.12.2016
Subjects
Luminescence
Synthesis
Topology
Zirconium
Online AccessGet full text

Cover

More Information
Summary:Two new MOFs denoted as M-CAU-24 (M = Zr, Ce) based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H TCPB) were obtained under mild reaction conditions within 15 min. The MOFs with composition [M (μ -O) (μ -OH) (OH) (H O) (TCPB) ] crystallise in the scu topology, a connectivity hitherto unreported for Zr-MOFs with tetracarboxylate linker molecules. Zr-CAU-24 exhibits UV/blue ligand-based luminescence.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt03852b