Potentials and challenges of high-field PFG NMR diffusion studies with sorbates in nanoporous media

• Published in: Adsorption : journal of the International Adsorption Society Vol. 27; no. 3; pp. 485 - 501
• Main Authors: Baniani, Amineh, Berens, Samuel J., Rivera, Matthew P., Lively, Ryan P., Vasenkov, Sergey
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.04.2021; Springer Nature B.V
• Subjects: Chemistry; Chemistry and Materials Science; Diffusion in Nanoporous Solids; Engineering Thermodynamics; Heat and Mass Transfer; Industrial Chemistry/Chemical Engineering; Magnetic fields; Membranes; Metal-organic frameworks; NMR; Nuclear magnetic resonance; Self diffusion; Single crystals; Sorbates; Surfaces and Interfaces; Thin Films; Zeolites; High field NMR; PFG NMR; MMMs; ZIFs; Normal diffusion; Anomalous diffusion
• ISSN: 0929-5607; 1572-8757
• DOI: 10.1007/s10450-020-00255-y

High magnetic fields (up to 17.6 T) in combination with large magnetic field gradients (up to 25 T/m) were successfully utilized in pulsed field gradient (PFG) NMR studies of gas and liquid diffusion in nanoporous materials. In this mini-review, we present selected examples of such studies demonstrating the ability of high field PFG NMR to gain unique insights and differentiate between various types of diffusion. These examples include identifying and explaining an anomalous relationship between molecular size and self-diffusivity of gases in a zeolitic imidazolate framework (ZIF), as well as revealing and explaining an influence of mixing different linkers in a ZIF on gas self-diffusion. Different types of normal and restricted self-diffusion were quantified in hybrid membranes formed by dispersing ZIF crystals in polymers. High field PFG NMR studies of such membranes allowed observing and explaining an influence of the ZIF crystal confinement in a polymer on intra-ZIF self-diffusion of gases. This technique also allowed measuring and understanding anomalous single-file diffusion (SFD) of mixed sorbates. Furthermore, the presented examples demonstrate a high potential of combining high field PFG NMR with single-crystal infrared microscopy (IRM) for obtaining greater physical insights into the studied diffusion processes.