ZnO/CeO2 nanocomposite with low photocatalytic activity as efficient UV filters

• Published in: Journal of materials science Vol. 55; no. 16; pp. 6834 - 6847
• Main Authors: Mueen, Rafid, Morlando, Alexander, Qutaish, Hamzeh, Lerch, Michael, Cheng, Zhenxiang, Konstantinov, Konstantin
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.06.2020; Springer Nature B.V
• Subjects: Catalytic activity; Cerium oxides; Characterization and Evaluation of Materials; Chemical Routes to Materials; Chemistry and Materials Science; Classical Mechanics; Crystallites; Crystallography and Scattering Methods; Materials Science; Nanocomposites; Nanoparticles; Photocatalysis; Polymer Sciences; Solar simulation; Solid Mechanics; Ultraviolet filters; Ultraviolet radiation; Zinc oxide
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-020-04493-x

In this study, we successfully synthesized ZnO/CeO 2 composite nanoparticles for efficient ultraviolet (UV) filtering applications using a simple precipitation route. Various ratios of Ce/Ti, 2.5 at.%, 5 at.%, and 10 at.% were used to precipitate ceria onto commercial ZnO nanopowder at pH 9. The calculated mean crystallite sizes of the resultant nanocomposites were ~ 90 nm, ~ 79 nm, and ~ 41 nm for the 2.5 at.%, 5 at.% and 10 at.% ceria amounts, respectively. A stronger and more selective absorbance within the UV range was observed due to precipitation of a small amount of ceria to decorate the commercial ZnO surface. The photocatalyst results show that the addition of ceria, particularly with the precipitation amount increased up to 10 at.%, can effectively reduce crystal violet degradation by about 97% in a period of time from 0 to 30 min when exposed to ultraviolet light over 30 min or by around 99% under solar simulation for 30 min.