Facile functionalization of a fully fluorescent perfluorophenyl BODIPY: photostable thiol and amine conjugates

Selective nucleophilic substitution on a perfluorophenyl unit comprising a BODIPY fluorophore using an alkanethiol or a primary amine offers a quantitative fluorophore labelling strategy, while retaining high photostability and emission quantum yields approaching unity.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 47; no. 37; pp. 10425 - 10427
Main Authors Vives, Guillaume, Giansante, Carlo, Bofinger, Robin, Raffy, Guillaume, Del Guerzo, Andre, Kauffmann, Brice, Batat, Pinar, Jonusauskas, Gediminas, McClenaghan, Nathan D.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 07.10.2011
Royal Society of Chemistry
Subjects
Amines - chemistry
Boron Compounds - chemistry
Chemistry
Chemistry, Multidisciplinary
Fluorescent Dyes - chemistry
Hydrocarbons, Fluorinated - chemistry
Optics
Physical Sciences
Physics
Science & Technology
Spectrometry, Fluorescence
Sulfhydryl Compounds - chemistry
DOMAIN
DYES
SPECTROSCOPY
LIGHT
CHEMISTRY
ENERGY-TRANSFER
ABSORPTION
DERIVATIVES
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Summary:Selective nucleophilic substitution on a perfluorophenyl unit comprising a BODIPY fluorophore using an alkanethiol or a primary amine offers a quantitative fluorophore labelling strategy, while retaining high photostability and emission quantum yields approaching unity.
Bibliography:ObjectType-Article-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc13778f