Evaluation of iron-based electrocatalysts for water oxidation - an on-line mass spectrometry approach

Using on-line mass spectrometry in combination with classical electroanalytical techniques makes it possible to reliably determine onset potentials and to distinguish between competing reactions such as oxygen evolution and carbon dioxide formation. Using these on-line MS methods, catalytic water ox...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 52; no. 12; pp. 2643 - 2646
Main Authors Kottrup, Konstantin G, Hetterscheid, Dennis G H
Format Journal Article
LanguageEnglish
Published England 01.01.2016
Subjects
Carbon dioxide
Catalysis
Electrocatalysts
Evolution
Formations
Mass spectrometry
On-line systems
Oxidation
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Summary:Using on-line mass spectrometry in combination with classical electroanalytical techniques makes it possible to reliably determine onset potentials and to distinguish between competing reactions such as oxygen evolution and carbon dioxide formation. Using these on-line MS methods, catalytic water oxidation activity was demonstrated for cis-[Fe(cyclam)Cl2]Cl (1) and [Fe(cyclamacetate)Cl] (2).
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ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc10092e