Chemical Approaches for Stabilizing Perovskite Solar Cells

• Published in: Advanced energy materials Vol. 10; no. 1
• Main Authors: Lee, Jin‐Wook, Park, Nam‐Gyu
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01.01.2020
• Subjects: Chemical bonds; Commercialization; extrinsic; intrinsic; Material properties; Optoelectronics; Organic chemistry; Perovskites; Photovoltaic cells; Solar cells; stability; Stability tests; Test procedures
• ISSN: 1614-6832; 1614-6840
• DOI: 10.1002/aenm.201903249

Chemical bonding dictates not only the optoelectronic properties of materials, but also the intrinsic and extrinsic stability of materials. Here, the causes of intrinsic and extrinsic instability of perovskite materials are reviewed considering their correlation with the unique chemical‐bonding nature of perovskite materials. There are a number of key standardized stability tests established by the International Electrotechnical Commission for commercialized photovoltaic modules. Based on these procedures, the possible causes and related mechanisms of the material degradation that can arise during the test procedures are identified, which are discussed in terms of their chemical bonds. Based on the understanding of the critical causes, promising strategies for mitigating the causes to enhance the stability of perovskite solar cells are summarized. The stability of the state‐of‐the‐art perovskite solar cells implies a need for the development of improved stability‐testing protocols to move onto the next stage toward commercialization. Causes of intrinsic and extrinsic instability of perovskite materials and related mechanisms are discussed in terms of their chemical‐bonding nature. Understanding the critical mechanisms rationalizes the chemical approaches to mitigate the degradation in perovskite solar cells.