Synthesis and Structure of a Novel Two-dimensional Manganese(II) Azide Complex with N-Methylimidazole

A novel two-dimensional manganese(II) azide complex with N-methyl-imidazole, [Mn(N-methyl-imidazole)2 (μ1,3-N3)2]n, was synthesized. The title complex was crystallized in the monoclinic system, space group P21/n with a = 6.5886(3)Å, b = 6.3101(3), c = 14.8922(7)Å, β = 94.301(1)°, V = 617.40(5)Å3 and...

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Published inAnalytical Sciences ; X-ray Structure and Analysis Online Vol. 23; pp. x175 - x176
Main Authors CHEN, Feng-juan, LIU, Guo-qi, XU, Zhi-hong, ZENG, Zheng-zhi
Format Journal Article
LanguageEnglish
Published Tokyo The Japan Society for Analytical Chemistry 2007
Japan Science and Technology Agency
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Summary:A novel two-dimensional manganese(II) azide complex with N-methyl-imidazole, [Mn(N-methyl-imidazole)2 (μ1,3-N3)2]n, was synthesized. The title complex was crystallized in the monoclinic system, space group P21/n with a = 6.5886(3)Å, b = 6.3101(3), c = 14.8922(7)Å, β = 94.301(1)°, V = 617.40(5)Å3 and Z = 2. The structure consists of an extended two-dimensional layer of octahedrally coordinated centrosymmetric manganese atoms, bridged by means of μ1,3-N3 ligands.
ISSN:1348-2238
1348-2238
1883-3578
DOI:10.2116/analscix.23.x175