Tantalum-Carbon Functionalities Bonded to a Calix[4]arene-Oxo Matrix: The Chemistry of Mono-, Dialkyl, and Butadiene Derivatives of Tantalum(V)

Tantalum–carbon functionalities bonded over an oxo matrix (here calix[4]arene anions) undergo a variety of multiple migratory insertion reactions which lead to the metal‐assisted formation of C–C and CC bonds.

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Bibliographic Details
Published inChemistry : a European journal Vol. 5; no. 2; pp. 722 - 737
Main Authors Castellano, Barbara, Solari, Euro, Floriani, Carlo, Re, Nazzareno, Chiesi-Villa, Angiola, Rizzoli, Corrado
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.02.1999
WILEY‐VCH Verlag
Wiley
Subjects
Butadiene
Calixarene
Chemistry
Chemistry, Multidisciplinary
Migratory insertion reactions
Physical Sciences
Science & Technology
Tantalum
Unsaturated ligands
GROUP-5 METAL CENTERS
BEHAVIOR
CRYSTAL-STRUCTURES
ETA-2-ACYL COMPLEXES
butadiene
migratory insertion reactions
ORGANOMETALLIC REACTIVITY
unsaturated ligands
ZIRCONIUM
P-TERT-BUTYLCALIX ARENE
DIENE COMPLEXES
ETA-2-IMINOACYL
OXO SURFACE
tantalum
calixarene
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Summary:Tantalum–carbon functionalities bonded over an oxo matrix (here calix[4]arene anions) undergo a variety of multiple migratory insertion reactions which lead to the metal‐assisted formation of C–C and CC bonds.
Bibliography:istex:B40093D63793A96280102E1A7D4B157DD738F01C
ArticleID:CHEM722
ark:/67375/WNG-L6PG525L-F
ISSN:0947-6539
1521-3765
DOI:10.1002/(SICI)1521-3765(19990201)5:2<722::AID-CHEM722>3.0.CO;2-Y