The melting temperature (or not melting) of poly(vinyl chloride)

• Published in: Journal of vinyl & additive technology Vol. 14; no. 3; pp. 105 - 109
• Main Author: Summers, James W.
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc., A Wiley Company 01.09.2008; Wiley; John Wiley & Sons, Inc
• Subjects: Applied sciences; Exact sciences and technology; Extrusion moulding; Machinery and processing; Moulding; Plastics; Polymer industry, paints, wood; Technology of polymers; Melting; Temperature effect; Capillary flow; Crystallinity; Processability; Experimental study; Phthalates; PVC plasticizer; Additive; Extrusion; Technological properties; Property structure relationship; Polyvinyl chloride
• ISSN: 1083-5601; 1548-0585
• DOI: 10.1002/vnl.20151

Abstract The best answer to what is the melting temperature of PVC is its previous processing temperature. That temperature is where secondary crystallites, created by gelation, melt and allow the primary particle flow units to flow again independently. In the case of powder compounds being processed for the first time, the question of melting is less relevant. The PVC, out of the polymerizer, contains crystallites that are not completely meltable. The issue is how easily the grains of PVC disperse to primary particle flow units. This property depends on polymerization conditions and the type of processing equipment. The temperature achieved affects the amount of fusion (gelation). J. VINYL ADDIT. TECHNOL., 2008. © 2008 Society of Plastics Engineers.