Crystal structure of γ-methyl L -glutamate N -carboxy anhydride

In the title compound, C 7 H 9 NO 5 , alternative name N -carboxy-L-glutamic anhydride γ-methyl ester, the oxazolidine ring is essentially planar with a maximum deviation of 0.020 (3) Å. In the crystal, molecules are linked by N—H...O hydrogen bonds between the imino group and the carbonyl O atom in...

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Published inActa crystallographica. Section E, Crystallographic communications Vol. 71; no. 1; pp. 48 - 50
Main Authors Kanazawa, Hitoshi, Inada, Aya, Sakon, Aya, Uekusa, Hidehiro
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.01.2015
Subjects
amino acid N-carboxy anhydrides
crystal structure
hydrogen bonding
polymerization
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Summary:In the title compound, C 7 H 9 NO 5 , alternative name N -carboxy-L-glutamic anhydride γ-methyl ester, the oxazolidine ring is essentially planar with a maximum deviation of 0.020 (3) Å. In the crystal, molecules are linked by N—H...O hydrogen bonds between the imino group and the carbonyl O atom in the methyl ester group, forming a tape structure along the a- axis direction. The tapes are linked by C—H...O interactions into a sheet parallel to the ac plane. The tapes are also stacked along the b axis with short contacts between the oxazolidine rings [C...O contact distances = 2.808 (4)–3.060 (4) Å], so that the oxazolidine rings are arranged in a layer parallel to the ab plane. This arrangement of the oxazolidine rings is very preferable for the polymerization of the title compound in the solid state.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989014026917