Effect of the Morphology of Sulfo Cation Exchangers on their Catalytic Properties in the Preparation of Ethyl tert-Butyl Ether

It was shown that the morphology of sulfo cationic exchange catalysts described by fractal geometry determines their characteristics in the heterogeneous catalytic synthesis of ethyl tert -butyl ether. It was established that catalysts with partial coverage of the support by the sulfo cation exchang...

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Published inTheoretical and experimental chemistry Vol. 49; no. 6; pp. 376 - 380
Main Authors Serebrii, T. G., Vlasenko, N. V., Kochkin, Yu. N., Strizhak, P. E.
Format Journal Article
LanguageEnglish
Published Boston Springer US 2014
Springer
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Telomerase
ethyl
sulfo cation exchanger
acidity
butyl ether
fractal dimensionality
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Summary:It was shown that the morphology of sulfo cationic exchange catalysts described by fractal geometry determines their characteristics in the heterogeneous catalytic synthesis of ethyl tert -butyl ether. It was established that catalysts with partial coverage of the support by the sulfo cation exchanger have higher selectivity and greater productivity in the active phase than catalysts with more than monolayer coverage.
ISSN:0040-5760
1573-935X
DOI:10.1007/s11237-014-9338-x