Analysis of Hydrogen Bonding Network in the Systems Containing Chloride-Based Ionic Liquids with Cellulose/Cellobiose by Fourier-Transform Infrared Spectroscopy

Hydrogen bonds formed upon dissolution of cellulose and cellobiose in ionic liquids, 1-butyl-3- methylpyridinium and 1-butyl-3-methylimidazolium chlorides, have been analyzed and characterized by means of Fourier-transform infrared spectroscopy and quantum-chemical calculation. The obtained data hav...

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Bibliographic Details
Published inRussian journal of general chemistry Vol. 88; no. 5; pp. 935 - 942
Main Authors Kashirskii, D. A., Sashina, E. S., Artamonova, T. V., Myznikov, L. V.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.05.2018
Springer
Springer Nature B.V
Subjects
Absorption spectra
Acetates
Analysis
Bonds
Cellulose
Chemical bonds
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Chlorides
Dichloropropane
Fourier transforms
Hydrogen
Hydrogen bonding
Hydrogen bonds
Hydrogen storage
Hydrogen-based energy
Infrared analysis
Infrared spectroscopy
Ionic liquids
Organic chemistry
Quantum chemistry
Spectrum analysis
ionic liquids
cellobiose
cellulose
hydrogen bond
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Summary:Hydrogen bonds formed upon dissolution of cellulose and cellobiose in ionic liquids, 1-butyl-3- methylpyridinium and 1-butyl-3-methylimidazolium chlorides, have been analyzed and characterized by means of Fourier-transform infrared spectroscopy and quantum-chemical calculation. The obtained data have been used for assignment of absorption bands of individual OH groups and determination of hydrogen bonds energy in the solutions.
ISSN:1070-3632
1608-3350
DOI:10.1134/S107036321805016X