Hetero-metallic Lanthanide CPs Involving Sodium: Synthesis, Crystal Structure, and Luminescence Properties

• Published in: Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 640; no. 11; pp. 2255 - 2260
• Main Authors: Nie, Zhi-Wen, Li, Sha-Sha, Zeng, Cheng-Hui, Wang, Lei, Li, Yuan, Yin, Shun-Gao, Zhong, Sheng-Liang
• Format: Journal Article
• Language: English; German
• Published: Weinheim WILEY-VCH Verlag 01.09.2014; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: Crystal structure; Hetero-metallic complexes; Lanthanide CPs; Luminescence properties; Sodium
• ISSN: 0044-2313; 1521-3749
• DOI: 10.1002/zaac.201400202

[TbNa(4‐msal)4(phen)2]n (1) (4‐msal = 4‐methyl salicylic acid), a new hetero‐metallic lanthanide coordination polymer (CP) involving sodium was synthesized. It crystallizes in the monoclinic space group P21/n, with a = 20.4809(9) Å, b = 9.8183(2) Å, c = 26.1987(11) Å, α = 90.00°, β = 112.922(5)°, γ = 90.00°, V = 4852.2(3) Å3, and Z = 4. The complex was characterized by single crystal and powder X‐ray diffraction, elemental analysis (EA), and Fourier transform infrared (FT‐IR) and luminescence spectroscopy. The luminescence properties of a powder sample of 1 were studied at room temperature and the luminescence lifetime and total quantum yield (QY) were determined.