Stability Enhancement of Zinc‐Ion Batteries Using Non‐Aqueous Electrolytes

• Published in: Batteries & supercaps Vol. 5; no. 5
• Main Authors: Kao‐ian, Wathanyu, Mohamad, Ahmad Azmin, Liu, Wei‐Ren, Pornprasertsuk, Rojana, Siwamogsatham, Siwaruk, Kheawhom, Soorathep
• Format: Journal Article
• Language: English
• Published: 01.05.2022
• Subjects: costs; deep eutectic solvent; ionic liquid; non-proton donor electrolyte; organic
• ISSN: 2566-6223; 2566-6223
• DOI: 10.1002/batt.202100361

Owing to their high energy density and low cost, zinc‐ion batteries (ZIBs) are gaining much in popularity. However, in practice, issues with hydrogen evolution, zinc dendrite development, corrosion, and passivation persist. Such drawbacks prove difficult to eradicate completely. To address these difficulties, many techniques have been proposed including inhibitor addition, artificial SEI, and Zn electrode modification. As a result, some researchers believe that using non‐proton donor electrolytes or nonaqueous electrolytes can fundamentally solve these problems. Herein, the efforts to apply nonaqueous electrolytes such as organic electrolytes, room‐temperature ionic liquids, and deep‐eutectic solvents to ZIBs are described. An understanding of the mechanisms of nonaqueous ZIBs (NZIBs) regarding zinc plating/stripping and intercalation/deintercalation is also highlighted. Importantly, research gaps are identified in order to pave the way for future study. In addition, an attempt is made to offer a viewpoint on critical topics as well as a benchmarking and enhancement of NZIB technologies. Non‐aqueous electrolyte for ZIB: Zinc‐ion batteries (ZIBs) are gaining much in popularity. However, in practice, issues with hydrogen evolution, zinc dendrite development, corrosion, and passivation persist. Herein, the efforts to apply non‐aqueous electrolytes in ZIBs are systematically reviewed. Furthermore, understanding non‐aqueous ZIBs (NZIBs) mechanisms regarding zinc plating/stripping and intercalation/deintercalation is also highlighted. Importantly, research gaps are identified to pave the way for future studies.