Efficient degradation of diclofenac by LaFeO3-Catalyzed peroxymonosulfate oxidation---kinetics and toxicity assessment

• Published in: Chemosphere (Oxford) Vol. 218; pp. 299 - 307
• Main Authors: Rao, Yongfang, Han, Fuman, Chen, Qian, Wang, Dan, Xue, Dan, Wang, Hua, Pu, Shengyan
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.03.2019
• Subjects: Degradation kinetic; Diclofenac; LaFeO3; Peroxylmonosulfate; Toxicity assessment; LaFeO3; Degradation kinetic; Peroxylmonosulfate; Toxicity assessment; Diclofenac
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2018.11.105

Diclofenac was frequently found in various waters, indicating conventional wastewater treatment methods ineffective in its removal. In this study, LaFeO3 (LFO) was synthesized and its catalytic activity of LFO as the activator of different oxidants such as persulfate (PS), hydrogen peroxide and peroxylmonosulfate (PMS) was evaluated in terms of DCF degradation. The influence of calcination temperature was examined on the catalytic activity of LFO. The effects of various parameters including pH levels, PMS concentration, LFO dose and initial DCF concentration were investigated on DCF degradation rate. The marginal effects of PMS concentration and LFO dose were compared. Langmuir-Hinshelwood (LH) model was used to quantitatively describe DCF degradation reaction in LFO/PMS system. The two constants, k (Limiting reaction rate at maximum coverage) and K (Equilibrium adsorption constant), were determined on the basis of LH model. The performance of LFO/PMS process was also estimated in the presence of various inorganic anions. The potential toxicity of LFO and PMS were evaluated using phytoplankton and the toxicity evolution during DCF degradation was also investigated using luminescent bacteria. This contribution provides a basic study regarding the potential application of heterogeneous PMS activation by perovskite LFO for both DCF removal and toxicity elimination. •The catalytic activity of LFO is contingent on the calcination temperature of LFO.•Diclofenac degradation rate depends on pH value, PMS and LFO dose.•The marginal effect of LFO dosage is larger than that of PMS concentration.•H2PO4− substantially inhibited DCF degradation.•Toxicity elimination of DCF can be achieved by LFO/PMS process.