( Z )-3-(4-Bromophenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one

The title compound, C21H19BrN2OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclohexene ring adopts a distorted half-chair conformation and the C—N bond lies in an equatorial orientation. The thiazolidine ring forms dihedral...

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Published inActa crystallographica. Section E, Structure reports online Vol. 68; no. 7; p. o1994
Main Authors Ooi, Chin Wei, Fun, Hoong-Kun, Quah, Ching Kheng, Sathishkumar, Murugan, Ponnuswamy, Alagusundaram
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.07.2012
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Summary:The title compound, C21H19BrN2OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclohexene ring adopts a distorted half-chair conformation and the C—N bond lies in an equatorial orientation. The thiazolidine ring forms dihedral angles of 53.76 (7) and 57.22 (7)° with the benzene and bromo-substituted benzene rings, respectively. The dihedral angle between the benzene and bromo-substituted benzene rings is 76.06 (7)°. In the crystal, inversion dimers linked by pairs of C—H...O hydrogen bonds generate R22(14) loops. The crystal is further consolidated by weak C—H...π interactions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812024646