Room temperature C-H bond activation on a [Pd(I)-Pd(I)] platform

Heteroatom assisted C-H bond activation of 2-substituted naphthyridines with solvated Pd(I)2(CH3CN)6(BF4)2 provides bi- and trinuclear Pd(II) cyclometalated complexes, which provide valuable insight into potential intermediates in palladium catalyzed direct arylation reactions.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 49; no. 84; pp. 9764 - 9766
Main Authors Sarkar, Mithun, Doucet, Henri, Bera, Jitendra K
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 28.10.2013
Subjects
Activation
Bonding
Catalysis
Chemical Sciences
Palladium
Platforms
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Summary:Heteroatom assisted C-H bond activation of 2-substituted naphthyridines with solvated Pd(I)2(CH3CN)6(BF4)2 provides bi- and trinuclear Pd(II) cyclometalated complexes, which provide valuable insight into potential intermediates in palladium catalyzed direct arylation reactions.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc44493g