Double Smiles rearrangement of Passerini adducts towards benzoxazinones

A new straightforward access to benzoxazinones based on a three-component coupling is presented here. The mechanism of the whole process involves a double aryl transfer as clearly underlined by the X-ray diffraction analysis of the products.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 50; no. 17; pp. 2214 - 2217
Main Authors Martinand-Lurin, E., Dos Santos, A., El Kaim, L., Grimaud, L., Retailleau, P.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2014
Royal Society of Chemistry
Subjects
Chemical Sciences
Chemistry
Chemistry, Multidisciplinary
Organic chemistry
Physical Sciences
Science & Technology
ALDEHYDES
ARYLATION
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Summary:A new straightforward access to benzoxazinones based on a three-component coupling is presented here. The mechanism of the whole process involves a double aryl transfer as clearly underlined by the X-ray diffraction analysis of the products.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc49022j