STRUCTURE OF 1-ETHYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE - MODEL FOR ROOM-TEMPERATURE MOLTEN-SALTS

The crystal structure of 1-ethyl-3-methylimidazolium (EMI(+)) hexafluorophosphate consists of interionic interactions dominated by cation-anion coulombic forces with minimal hydrogen bonding and serves as a model for EMI(+) room temperature molten salts containing weakly complexing anions.

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Bibliographic Details
Published inJournal of the Chemical Society. Chemical communications no. 3; pp. 299 - 300
Main Authors FULLER, J, CARLIN, RT, DELONG, HC, HAWORTH, D
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 1994
Royal Society of Chemistry
Subjects
Chemistry
Chemistry, Multidisciplinary
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Heterocyclic compounds
Organic compounds
Physical Sciences
Physics
Science & Technology
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
X-ray absorption spectroscopy: exafs, nexafs, xanes, etc
X-ray diffraction and scattering
IONIC LIQUIDS
CHLORIDE
Five membered ring
Organic cation
Molecular structure
Nitrogen heterocycle
Iminium compounds
XRD
Experimental study
Organic compounds
Crystal structure
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Summary:The crystal structure of 1-ethyl-3-methylimidazolium (EMI(+)) hexafluorophosphate consists of interionic interactions dominated by cation-anion coulombic forces with minimal hydrogen bonding and serves as a model for EMI(+) room temperature molten salts containing weakly complexing anions.
ISSN:0022-4936
DOI:10.1039/c39940000299