TERTIARY PHOSPHINES AND P-CHIRAL PHOSPHINITES BEARING A FULLERENE SUBSTITUENT

The reaction of a lithiated phosphine-borane or a posphinite borane with C-60 followed by removal of the BH3 group affords a phosphine or a phosphinite bearing a fullerene substituent, wh ich undergoes complexation with BH3 a nd PtCl2 selectively on the phosphorus atom with 1:1 and 2:1 stoichiometry...

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Bibliographic Details
Published inJournal of the Chemical Society. Chemical communications no. 18; pp. 2093 - 2094
Main Authors YAMAGO, S, YANAGAWA, M, NAKAMURA, E
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 1994
Royal Society of Chemistry
Subjects
Alicyclic compounds
Alicyclic compounds, terpenoids, prostaglandins, steroids
Chemistry
Chemistry, Multidisciplinary
Exact sciences and technology
Organic chemistry
Physical Sciences
Preparations and properties
Science & Technology
C60
BORANES
BOND
METAL-COMPLEXES
Organic phosphinite
Addition reaction
Fullerenes
Atomic cluster
Tertiary phosphine
Chemical reactivity
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Summary:The reaction of a lithiated phosphine-borane or a posphinite borane with C-60 followed by removal of the BH3 group affords a phosphine or a phosphinite bearing a fullerene substituent, wh ich undergoes complexation with BH3 a nd PtCl2 selectively on the phosphorus atom with 1:1 and 2:1 stoichiometry.
ISSN:0022-4936
DOI:10.1039/c39940002093