6-Methylpyridin-2-amine

In the title molecule, C6H8N2, the endocyclic angles are in the range 118.43 (9)–122.65 (10)°. The molecular skeleton is planar (r.m.s. deviation = 0.007 Å). One of the two amino H atoms is involved in an N—H...N hydrogen bond, form...

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Published inActa crystallographica. Section E, Structure reports online Vol. 68; no. 12; p. o3466
Main Authors Draguta, Sergiu, Khrustalev, Victor N., Sandhu, Bhupinder, Antipin, Mikhail Yu, Timofeeva, Tatiana V.
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.12.2012
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Summary:In the title molecule, C6H8N2, the endocyclic angles are in the range 118.43 (9)–122.65 (10)°. The molecular skeleton is planar (r.m.s. deviation = 0.007 Å). One of the two amino H atoms is involved in an N—H...N hydrogen bond, forming an inversion dimer, while the other amino H atom participates in N—H...π interactions between the dimers, forming layers parallel to (100).
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812047800