Manganese‐Catalysed Dehydrogenative Coupling – An Overview

Manganese‐catalysed reactions have attracted great attention recently due to the high relative abundance and cheap and eco‐friendly behaviour. Applications of manganese catalysis in cross‐dehydrogenative coupling are among the hottest areas since 90% of the contributions are very recent. Dehydrogena...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 362; no. 8; pp. 1602 - 1650
Main Authors Rohit, K. R., Radhika, Sankaran, Saranya, Salim, Anilkumar, Gopinathan
Format Journal Article
LanguageEnglish
Published Heidelberg Wiley Subscription Services, Inc 17.04.2020
Subjects
Alcohols
Alkenes
Amines
Carbonyl compounds
Carbonyls
Chemical reactions
Couplings
Cross coupling
C−H activation
Dehydrogenation
dehydrogenative coupling
Imines
Manganese
manganese catalysis
pincer complexes
radicals
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Summary:Manganese‐catalysed reactions have attracted great attention recently due to the high relative abundance and cheap and eco‐friendly behaviour. Applications of manganese catalysis in cross‐dehydrogenative coupling are among the hottest areas since 90% of the contributions are very recent. Dehydrogenation of alcohols using Mn‐pincer systems is highly explored nowadays for cross‐coupling to synthesise a variety of products and Mn‐catalysed C−H activation, and radical reactions are applied in dehydrogenative couplings of various synthons. This review focuses on the synthesis of synthetically as well as biologically important motifs such as carbonyl compounds, olefins, nitrogen heterocycles, amines, imines, etc. using manganese‐catalysed dehydrogenative cross‐coupling reactions.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201901389