Electrochemical Oxidative Cross‐Coupling Reaction to Access Unsymmetrical Thiosulfonates and Selenosulfonates

The electrochemical oxidative cross‐dehydrogenative coupling of arylsulfinic acids with thiophenols was achieved via a radical process. A wide range of arylsulfinic acids and substituted thiophenols were found to be tolerated, providing unsymmetrical thiosulfonates in good to excellent yields. This...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 361; no. 9; pp. 2014 - 2019
Main Authors Zhang, Xiaofeng, Cui, Ting, Zhang, Yanghao, Gu, Weijin, Liu, Ping, Sun, Peipei
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 23.04.2019
Wiley Subscription Services, Inc
Subjects
arylsulfinic acids
Chemistry
Chemistry, Applied
Chemistry, Organic
Coupling
Dehydrogenation
Electrochemistry
oxidative cross-coupling
Physical Sciences
Science & Technology
Selenides
selenosulfonates
thiosulfonates
THIOLS
oxidative cross-coupling
thiosulfonates
selenosulfonates
Electrochemistry
arylsulfinic acids
DISULFIDES
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Summary:The electrochemical oxidative cross‐dehydrogenative coupling of arylsulfinic acids with thiophenols was achieved via a radical process. A wide range of arylsulfinic acids and substituted thiophenols were found to be tolerated, providing unsymmetrical thiosulfonates in good to excellent yields. This electrochemical method can also be used for the reaction of arylsulfinic acids with disulfides or diselenides to obtain thiosulfonates or selenosulfonates.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201900047