A Homoleptic Carbene-Lithium Complex

Rarity value is something that main group complexes of N‐heterocyclic carbenes still have. With a triscarbene chelating carbon analogue of Trofimenko's tris(pyrazolyl)borate the solvent free, dinuclear lithium complex 1 was successfully synthesized, in which the lithium atoms are only bound to...

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Published inAngewandte Chemie International Edition Vol. 40; no. 10; pp. 1907 - 1910
Main Authors Fränkel, Robert, Birg, Christine, Kernbach, Ulrich, Habereder, Tassilo, Nöth, Heinrich, Fehlhammer, Wolf P.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 18.05.2001
WILEY‐VCH Verlag GmbH
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Summary:Rarity value is something that main group complexes of N‐heterocyclic carbenes still have. With a triscarbene chelating carbon analogue of Trofimenko's tris(pyrazolyl)borate the solvent free, dinuclear lithium complex 1 was successfully synthesized, in which the lithium atoms are only bound to carbene carbon atoms.
Bibliography:ark:/67375/WNG-FWVSX4ML-N
ArticleID:ANIE1907
istex:10EB00F7204F0EFD79EF0C1C158D9261B266C9BF
14
Homoleptic carbene complexes part 10. This work was supported by the Fonds der Chemischen Industrie, the Deutsche Forschungsgemeinschaft, and by the Studienstiftung des Deutschen Volkes. Part 9 ref.
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X‐ray analysis
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20010518)40:10<1907::AID-ANIE1907>3.0.CO;2-1