The First Dectection of Peroxo and Bis-superoxo Complexes of Aluminum: FAlO2 and FAlO4

A photolytically induced reaction of AlF with O2 in an argon matrix afforded the first peroxo and bis‐superoxo complexes of aluminum: FAlO2 and FAl(O2)2 (see picture). The compounds were identified and characterized by IR spectroscopy and density functional theory (DFT) as well as ab initio calculat...

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Published inAngewandte Chemie (International ed.) Vol. 40; no. 24; pp. 4696 - 4700
Main Authors Bahlo, Jan, Himmel, Hans-Jörg, Schnöckel, Hansgeorg
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 17.12.2001
WILEY‐VCH Verlag GmbH
Subjects
aluminum
matrix isolation
peroxo ligands
photolysis
superoxo ligands
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Summary:A photolytically induced reaction of AlF with O2 in an argon matrix afforded the first peroxo and bis‐superoxo complexes of aluminum: FAlO2 and FAl(O2)2 (see picture). The compounds were identified and characterized by IR spectroscopy and density functional theory (DFT) as well as ab initio calculations.
Bibliography:istex:374CF73121411108C7CF833B04F6105758F1DFCB
ArticleID:ANIE4696
ark:/67375/WNG-59T3DVSX-N
We thank Professor R. Ahlrichs for fruitful discussions and the Deutsche Forschungsgemeinschaft for the award of an Habilitation grant to H.‐J.H.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20011217)40:24<4696::AID-ANIE4696>3.0.CO;2-W