The First Dectection of Peroxo and Bis-superoxo Complexes of Aluminum: FAlO2 and FAlO4
A photolytically induced reaction of AlF with O2 in an argon matrix afforded the first peroxo and bis‐superoxo complexes of aluminum: FAlO2 and FAl(O2)2 (see picture). The compounds were identified and characterized by IR spectroscopy and density functional theory (DFT) as well as ab initio calculat...
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Published in | Angewandte Chemie (International ed.) Vol. 40; no. 24; pp. 4696 - 4700 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag GmbH
17.12.2001
WILEY‐VCH Verlag GmbH |
Subjects | |
Online Access | Get full text |
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Summary: | A photolytically induced reaction of AlF with O2 in an argon matrix afforded the first peroxo and bis‐superoxo complexes of aluminum: FAlO2 and FAl(O2)2 (see picture). The compounds were identified and characterized by IR spectroscopy and density functional theory (DFT) as well as ab initio calculations. |
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Bibliography: | istex:374CF73121411108C7CF833B04F6105758F1DFCB ArticleID:ANIE4696 ark:/67375/WNG-59T3DVSX-N We thank Professor R. Ahlrichs for fruitful discussions and the Deutsche Forschungsgemeinschaft for the award of an Habilitation grant to H.‐J.H. |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/1521-3773(20011217)40:24<4696::AID-ANIE4696>3.0.CO;2-W |