Supercritical fluid fractionation of thermally oxidized canola oil
Supercritical fluid extraction procedures were developed to fractionate thermally oxidized canola oil. Canola oil was heated in a sealed glass ampoule for 72 h at 200°C in a forced‐convection oven. After heating, the percentages of triacylglycerol (TAG) trimer, dimer, monomer and lowermolecular weig...
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| Published in | Journal of the American Oil Chemists' Society Vol. 71; no. 6; pp. 615 - 618 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Berlin/Heidelberg
Springer‐Verlag
01.06.1994
Springer |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Supercritical fluid extraction procedures were developed to fractionate thermally oxidized canola oil. Canola oil was heated in a sealed glass ampoule for 72 h at 200°C in a forced‐convection oven. After heating, the percentages of triacylglycerol (TAG) trimer, dimer, monomer and lowermolecular weight (LMW) compounds in the heated oil sample (as determined by high‐performance size‐exclusion chromatography) were 3.0, 8.4, 81.3 and 7.3%, respectively. The LMW compounds included diacylglycerols, monoacylglycerols and free fatty acids. Fractions of TAG monomer of approximately 98% purity were isolated after extraction at 408 atm for 45 min. After a second extraction at 442 atm for 45 min, a TAG dimer fraction of 95% purity was isolated. Recoveries of TAG monomer and dimer were 96 and 87%, respectively. |
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| AbstractList | Abstract
Supercritical fluid extraction procedures were developed to fractionate thermally oxidized canola oil. Canola oil was heated in a sealed glass ampoule for 72 h at 200°C in a forced‐convection oven. After heating, the percentages of triacylglycerol (TAG) trimer, dimer, monomer and lowermolecular weight (LMW) compounds in the heated oil sample (as determined by high‐performance size‐exclusion chromatography) were 3.0, 8.4, 81.3 and 7.3%, respectively. The LMW compounds included diacylglycerols, monoacylglycerols and free fatty acids. Fractions of TAG monomer of approximately 98% purity were isolated after extraction at 408 atm for 45 min. After a second extraction at 442 atm for 45 min, a TAG dimer fraction of 95% purity was isolated. Recoveries of TAG monomer and dimer were 96 and 87%, respectively. Supercritical fluid extraction procedures were developed to fractionate thermally oxidized canola oil. Canola oil was heated in a sealed glass ampoule for 72 h at 200 degree C in a forced-convection oven. After heating, the percentages of triacylglycerol (TAG) trimer, dimer, monomer and lower-molecular weight (LMW) compounds in the heated oil sample (as determined by high-performance size-exclusion chromatography) were 3.0, 8.4, 81.3 and 7.3%, respectively. The LMW compounds included diacylglycerols, monoacylglycerols and free fatty acids. Fractions of TAG monomer of approximately 98% purity were isolated after extraction at 408 atm for 45 min. After a second extraction at 442 atm for 45 min, a TAG dimer fraction of 95% purity was isolated. Recoveries of TAG monomer and dimer were 96 and 87%, respectively. Supercritical fluid extraction procedures were developed to fractionate thermally oxidized canola oil. Canola oil was heated in a sealed glass ampoule for 72 h at 200°C in a forced‐convection oven. After heating, the percentages of triacylglycerol (TAG) trimer, dimer, monomer and lowermolecular weight (LMW) compounds in the heated oil sample (as determined by high‐performance size‐exclusion chromatography) were 3.0, 8.4, 81.3 and 7.3%, respectively. The LMW compounds included diacylglycerols, monoacylglycerols and free fatty acids. Fractions of TAG monomer of approximately 98% purity were isolated after extraction at 408 atm for 45 min. After a second extraction at 442 atm for 45 min, a TAG dimer fraction of 95% purity was isolated. Recoveries of TAG monomer and dimer were 96 and 87%, respectively. |
| Author | Artz W.E Hansen S.L |
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| Cites_doi | 10.1016/0021-9673(92)80176-U 10.1007/BF02672374 10.1007/BF02544019 10.1007/BF02665370 10.1021/j100212a041 10.1007/BF02542558 10.1007/BF02540927 10.1007/BF03022759 10.1007/BF02640495 10.1007/BF02543976 10.1007/BF02660595 10.1021/jf00099a017 10.1007/BF02636108 10.1007/BF03022761 10.1093/chromsci/27.7.355 10.2116/bunsekikagaku.39.2_79 10.1007/BF02672052 10.1007/BF03022762 10.1007/BF02546041 10.1002/jsfa.2740540413 10.1016/S0315-5463(85)71916-5 10.1016/0008-6223(91)90072-Q |
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| Keywords | Separation method Heat treatment Extraction process Carbon dioxide Gel filtration Canola oil Supercritical solvent Triglyceride |
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| References | 1984; 62 1985; 28 1991; 29 1989; 66 1973; 50 1991; 26 1986; 63 1991; 45 1990; 38 1978; 55 1991; 68 1991; 54 1990; 39 1982; 86 1988; 65 1981; 58 1974; 1 1985 1992; 69 1992; 20 1992; 609 1989; 27 1991; 9 1989; 25 Majors R.E. (e_1_2_1_23_1) 1991; 9 Pipkin W. (e_1_2_1_24_1) 1992; 20 Suzuki Y. (e_1_2_1_27_1) 1989; 25 White P.J. (e_1_2_1_15_1) 1991; 45 e_1_2_1_20_1 Alim H. (e_1_2_1_10_1) 1974; 1 e_1_2_1_21_1 e_1_2_1_22_1 e_1_2_1_28_1 e_1_2_1_25_1 Nawar W.W. (e_1_2_1_13_1) 1985 e_1_2_1_26_1 e_1_2_1_29_1 e_1_2_1_7_1 e_1_2_1_8_1 e_1_2_1_30_1 e_1_2_1_5_1 e_1_2_1_6_1 e_1_2_1_3_1 e_1_2_1_12_1 e_1_2_1_4_1 e_1_2_1_2_1 e_1_2_1_11_1 e_1_2_1_16_1 e_1_2_1_17_1 e_1_2_1_14_1 e_1_2_1_9_1 e_1_2_1_18_1 e_1_2_1_19_1 |
| References_xml | – volume: 54 start-page: 619 year: 1991 publication-title: J. Sci. Food Agric. – volume: 66 start-page: 1338 year: 1989 publication-title: Am. Oil Chem. Soc. – volume: 86 start-page: 3016 year: 1982 publication-title: J. Phys. Chem. – volume: 26 start-page: 23 year: 1991 publication-title: Lipids – volume: 45 start-page: 75 year: 1991 publication-title: Food Technol. – volume: 1 start-page: 345 year: 1974 publication-title: Proc. IV Int. Congr. Food Sci. Technol. – volume: 20 start-page: 14 year: 1992 publication-title: LC‐GC – volume: 66 start-page: 1360 year: 1989 publication-title: J. Am. Oil Chem. Soc. – volume: 39 start-page: 79 year: 1990 publication-title: Bunseki Kagaku – volume: 25 start-page: 439 year: 1989 publication-title: Rionbunshu – volume: 66 start-page: 1353 year: 1989 publication-title: J. Am. Oil Chem. Soc. – volume: 27 start-page: 355 year: 1989 publication-title: J. Chrom. Sci. – volume: 63 start-page: 914 year: 1986 publication-title: Am. Oil Chem. Soc. – volume: 65 start-page: 101 year: 1988 publication-title: Am. Oil Chem. Soc. – volume: 55 start-page: 728 year: 1978 publication-title: J. Am. Oil Chem. Soc. – volume: 62 start-page: 87 year: 1984 publication-title: Am. Oil Chem. Soc. – volume: 50 start-page: 223 year: 1973 publication-title: J. Am. Oil Chem. Soc. – volume: 63 start-page: 332 year: 1986 publication-title: J. Am. Oil Chem. Soc. – volume: 69 start-page: 557 year: 1992 publication-title: J. Am. Oil Chem. Soc. – volume: 26 start-page: 221 year: 1991 publication-title: Lipids – volume: 68 start-page: 822 year: 1991 publication-title: J. Am. Oil Chem. Soc. – volume: 58 start-page: 602 year: 1981 publication-title: J. Am. Oil Chem. Soc. – volume: 28 start-page: 197 year: 1985 publication-title: Can. Inst. Food Sci. Technol. J. – volume: 29 start-page: 215 year: 1991 publication-title: Carbon – start-page: 39 year: 1985 end-page: 60 – volume: 9 start-page: 78 year: 1991 publication-title: LC‐GC – volume: 38 start-page: 1862 year: 1990 publication-title: J. Agric. Food Chem. – volume: 609 start-page: 321 year: 1992 publication-title: J. Chromat. – volume: 20 start-page: 14 year: 1992 ident: e_1_2_1_24_1 publication-title: LC‐GC contributor: fullname: Pipkin W. – ident: e_1_2_1_29_1 doi: 10.1016/0021-9673(92)80176-U – ident: e_1_2_1_22_1 doi: 10.1007/BF02672374 – ident: e_1_2_1_18_1 doi: 10.1007/BF02544019 – ident: e_1_2_1_9_1 doi: 10.1007/BF02665370 – ident: e_1_2_1_25_1 doi: 10.1021/j100212a041 – volume: 25 start-page: 439 year: 1989 ident: e_1_2_1_27_1 publication-title: Rionbunshu contributor: fullname: Suzuki Y. – ident: e_1_2_1_4_1 doi: 10.1007/BF02542558 – volume: 45 start-page: 75 year: 1991 ident: e_1_2_1_15_1 publication-title: Food Technol. contributor: fullname: White P.J. – ident: e_1_2_1_3_1 doi: 10.1007/BF02540927 – start-page: 39 volume-title: Flavor Chemistry of Lipid Foods year: 1985 ident: e_1_2_1_13_1 contributor: fullname: Nawar W.W. – ident: e_1_2_1_5_1 doi: 10.1007/BF03022759 – ident: e_1_2_1_7_1 doi: 10.1007/BF02640495 – ident: e_1_2_1_12_1 doi: 10.1007/BF02543976 – volume: 1 start-page: 345 year: 1974 ident: e_1_2_1_10_1 publication-title: Proc. IV Int. Congr. Food Sci. Technol. contributor: fullname: Alim H. – volume: 9 start-page: 78 year: 1991 ident: e_1_2_1_23_1 publication-title: LC‐GC contributor: fullname: Majors R.E. – ident: e_1_2_1_17_1 doi: 10.1007/BF02660595 – ident: e_1_2_1_6_1 doi: 10.1021/jf00099a017 – ident: e_1_2_1_19_1 doi: 10.1007/BF02636108 – ident: e_1_2_1_20_1 doi: 10.1007/BF03022761 – ident: e_1_2_1_11_1 doi: 10.1007/BF02544019 – ident: e_1_2_1_30_1 doi: 10.1093/chromsci/27.7.355 – ident: e_1_2_1_26_1 doi: 10.2116/bunsekikagaku.39.2_79 – ident: e_1_2_1_2_1 doi: 10.1007/BF02672052 – ident: e_1_2_1_21_1 doi: 10.1007/BF03022762 – ident: e_1_2_1_16_1 doi: 10.1007/BF02546041 – ident: e_1_2_1_8_1 doi: 10.1002/jsfa.2740540413 – ident: e_1_2_1_14_1 doi: 10.1016/S0315-5463(85)71916-5 – ident: e_1_2_1_28_1 doi: 10.1016/0008-6223(91)90072-Q |
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| SubjectTerms | aceite de colza Biological and medical sciences calentamiento chauffage corps gras Fat industries fats Food industries fraccionamiento fractionation fractionnement Fundamental and applied biological sciences. Psychology grasas Heated oil heating high‐performance size‐exclusion chromatography huile de colza light‐scattering detector molecular weight oxidacion oxidation oxydation peso molecular poids moleculaire polymerization rapeseed oil supercritical fluid extraction and fractionation trigliceridos triglyceride triglycerides |
| Title | Supercritical fluid fractionation of thermally oxidized canola oil |
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