Cobalt(II)‐Catalyzed Bisfunctionalization of Alkenes with Diarylphosphine Oxide and Peroxide

• Published in: Advanced synthesis & catalysis Vol. 361; no. 22; pp. 5198 - 5209
• Main Authors: Shen, Jian, Xiao, Bo, Hou, Yang, Wang, Xue, Li, Gui‐Zhi, Chen, Jin‐Chun, Wang, Wei‐Li, Cheng, Jian‐Bo, Yang, Bin, Yang, Shang‐Dong
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 19.11.2019; Wiley Subscription Services, Inc
• Subjects: Alkenes; Chemistry; Chemistry, Applied; Chemistry, Organic; cobalt-catalyzed; difunctionalization; peroxidation; Peroxides; phosphonation; Physical Sciences; radicals; Science & Technology; ROOM-TEMPERATURE; STYRENES; phosphonation; radicals; cobalt-catalyzed; difunctionalization; CATALYZED CARBONYLATION-PEROXIDATION; CASCADE; ALPHA; ALDEHYDES; PHOSPHORUS-CENTERED RADICALS; peroxidation; ALKYLATION-PEROXIDATION; CYCLIZATION
• ISSN: 1615-4150; 1615-4169
• DOI: 10.1002/adsc.201900873

The low‐cost cobalt(II) catalyst has been used for the first time to achieve P(O)‐radical‐mediated bisfunctionalization of alkenes with diarylphosphine oxide and peroxides. This simple process is performed under mild conditions to afford a wide variety of phosphonation‐peroxidation products in a one...