Cobalt(II)‐Catalyzed Bisfunctionalization of Alkenes with Diarylphosphine Oxide and Peroxide

The low‐cost cobalt(II) catalyst has been used for the first time to achieve P(O)‐radical‐mediated bisfunctionalization of alkenes with diarylphosphine oxide and peroxides. This simple process is performed under mild conditions to afford a wide variety of phosphonation‐peroxidation products in a one...

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Published inAdvanced synthesis & catalysis Vol. 361; no. 22; pp. 5198 - 5209
Main Authors Shen, Jian, Xiao, Bo, Hou, Yang, Wang, Xue, Li, Gui‐Zhi, Chen, Jin‐Chun, Wang, Wei‐Li, Cheng, Jian‐Bo, Yang, Bin, Yang, Shang‐Dong
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 19.11.2019
Wiley Subscription Services, Inc
Subjects
Alkenes
Chemistry
Chemistry, Applied
Chemistry, Organic
cobalt-catalyzed
difunctionalization
peroxidation
Peroxides
phosphonation
Physical Sciences
radicals
Science & Technology
ROOM-TEMPERATURE
STYRENES
phosphonation
radicals
cobalt-catalyzed
difunctionalization
CATALYZED CARBONYLATION-PEROXIDATION
CASCADE
ALPHA
ALDEHYDES
PHOSPHORUS-CENTERED RADICALS
peroxidation
ALKYLATION-PEROXIDATION
CYCLIZATION
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Summary:The low‐cost cobalt(II) catalyst has been used for the first time to achieve P(O)‐radical‐mediated bisfunctionalization of alkenes with diarylphosphine oxide and peroxides. This simple process is performed under mild conditions to afford a wide variety of phosphonation‐peroxidation products in a one‐pot manner. Computational studies are carried out to provide a theoretical support for the P(O)‐radical‐involved bisfunctionalization of alkenes.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201900873