Electrochemical Three‐Component 1,2‐Aminosulfonylation of Alkenes: Entry to 2‐sulfonylethan‐1‐amines

A new electrochemical intermolecular 1,2‐aminosulfonylation of alkenes with sulfinates and amines is achieved by utilizing balanced three‐component interactions and reactivity differentiation. This strategy can be applicable to a wide range of amines, including primary and secondary amines, thus ena...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 361; no. 7; pp. 1538 - 1542
Main Authors Luo, Mu‐Jia, Liu, Bang, Li, Yang, Hu, Ming, Li, Jin‐Heng
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 01.04.2019
Wiley Subscription Services, Inc
Subjects
2-sulfonylethan-1-amines
Alkenes
Amines
Catalysis
Catalysts
Chemistry
Chemistry, Applied
Chemistry, Organic
difunctionalization
electrochemistry
Organic chemistry
Oxidizing agents
Physical Sciences
Science & Technology
sulfinates
electrochemistry
sulfinates
difunctionalization
SULFONES
alkenes
AEROBIC OXYSULFONYLATION
SULFINIC ACIDS
POTENT
2-sulfonylethan-1-amines
OLEFINS
DIAZIDATION
INHIBITORS
OXIDATIVE AMINATION
EFFICIENT
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Summary:A new electrochemical intermolecular 1,2‐aminosulfonylation of alkenes with sulfinates and amines is achieved by utilizing balanced three‐component interactions and reactivity differentiation. This strategy can be applicable to a wide range of amines, including primary and secondary amines, thus enabling alkene aminosulfonylation for producing diverse functionalized 2‐sulfonylethan‐1‐amines without the need of additive redox catalysts, metal catalysts and chemical oxidants.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201801492