Wet coprecipitation preparation of perovskite-type iron manganite nano powder pure phase using nitrate precursors: structural, opto-electronic, morphological and photocatalytic activity for degradation of Nile blue dye

• Published in: Journal of materials science. Materials in electronics Vol. 28; no. 14; pp. 10270 - 10276
• Main Authors: Habibi, Mohammad Hossein, Mosavi, Vala
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.07.2017; Springer Nature B.V
• Subjects: Catalytic activity; Characterization and Evaluation of Materials; Chemistry and Materials Science; Coprecipitation; Diffuse reflectance spectroscopy; Dyes; Emission analysis; Field emission microscopy; Heat treatment; Iron; Manganites; Materials Science; Morphology; Nanoparticles; Optical and Electronic Materials; Optoelectronics; Particle size distribution; Perovskite structure; Perovskites; Photocatalysis; Photodegradation; Precursors; Spectrum analysis; X-ray diffraction; Manganite; Field Emission Scanning Electron Microscope; Nile Blue; Photocatalytic Activity; Solar Light
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-017-6794-9

A pure phase of iron manganite nano powder has been prepared by the wet coprecipitation route using nitrate precursors subject to heat treatment at 650 °C for 4 h in air. The structural, opto-electronic, thermal and morphological properties of iron manganite nano powder were investigated by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDX), and UV–Vis diffuse reflectance spectroscopy (UV–Vis DRS). XRD results showed that a pure phase nano powder iron manganite with perovskite-type structure is formed. FESEM results showed that an average size of the iron manganite nano particles at about 64 nm with a narrow particle size distribution. UV–vis DRS reveal the optical band gap of 1.901 eV (652 nm) with a strong absorption at visible region of solar light. The photcatalytic activity of pure phase nano powder iron manganite perovskite catalyst displayed an excellect activity in degradation of Nile blue organic dye with 95% efficiency and 86% TOC removal in 80 min of irradiation.