Effects of Fe on catalytic hydrogenation of palm oil in aqueous solution

• Published in: Chemical papers Vol. 71; no. 1; pp. 119 - 126
• Main Authors: Wu, Li-Hua, Nordin, Mohd Ridzuan, Yaakob, Zahira, Liew, Kong-Yong, Li, Jin-Lin
• Format: Journal Article
• Language: English
• Published: Cham Springer International Publishing 2017; Springer Nature B.V
• Subjects: Ambient temperature; Aqueous solutions; Bimetals; Biochemistry; Biotechnology; Catalysis; Catalytic activity; Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Chitosan; Conversion; Hydrogenation; Industrial Chemistry/Chemical Engineering; Iron; Materials Science; Medicinal Chemistry; Nanoparticles; Original Paper; Palladium; Palm oil; Platinum; Selectivity; Nanoparticles; fatty acid; Palm oil; Hydrogenation; Fe
• ISSN: 2585-7290; 0366-6352; 1336-9075
• DOI: 10.1007/s11696-016-0063-x

Chitosan-stabilised metallic Pd (CTS-Pd) and Pt (CTS-Pt) nanoparticles were synthesised and used for the hydrogenation of palm oil. With the goal of preparing hydrogenated oil with low trans fatty acid (TFA) content under ambient conditions, Fe anion was added as the secondary metallic precursor to synthesise chitosan-stabilised bimetallic Pd–Fe (CTS-Pd–Fe) and Pt–Fe (CTS-Pt–Fe) nanoparticles. The catalytic hydrogenations with newly prepared nanoparticles were performed in aqueous solution under ambient temperature and atmospheric pressure. The addition of Fe was found to improve the catalytic activity and decrease the selectivity for TFA. Hydrogenation with CTS-Pt–Fe affords the optimal results, producing 3.8% TFA at 92.1% conversion of C 18:2 and no TFA was formed until the content of C 18:2 was lower than 1.7%. Based on the analyses, it can be demonstrated that the preferential conversion of C 18:2 to cis C 18:1 and cis C 18:1 to C 18:0 leads to the low formation of TFA.