Heteroleptic tris-cyclometalated iridium(III) complexes supported by an o-carboranyl-pyridine ligand

Heteroleptic tris-cyclometalated Ir(III) complexes supported by the o-carboranyl-pyridine (CBpy) as a novel C^N chelating ligand were synthesized and characterized. While the CBpy ligand contributes to the electronic stabilization of complexes, their photophysical properties are dominated by 2-arylp...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 42; no. 24; pp. 8549 - 8552
Main Authors Bae, Hye Jin, Kim, Hyungjun, Lee, Kang Mun, Kim, Taewon, Eo, Maengsun, Lee, Yoon Sup, Do, Youngkyu, Lee, Min Hyung
Format Journal Article
LanguageEnglish
Published England 28.06.2013
Subjects
Electronics
Ligands
Stabilization
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Summary:Heteroleptic tris-cyclometalated Ir(III) complexes supported by the o-carboranyl-pyridine (CBpy) as a novel C^N chelating ligand were synthesized and characterized. While the CBpy ligand contributes to the electronic stabilization of complexes, their photophysical properties are dominated by 2-arylpyridine ligands.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c3dt51019k