Rhodium-catalyzed C–C coupling reactions via double C–H activation

Various rhodium-catalyzed double C–H activations are reviewed. These powerful strategies have been developed to construct C–C bonds, which might be widely embedded in complex aza-fused heterocycles, polycyclic skeletons and heterocyclic scaffolds. In particular, rhodium( iii ) catalysis shows good s...

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Published inOrganic & biomolecular chemistry Vol. 14; no. 20; pp. 4554 - 4570
Main Authors Li, Shuai-Shuai, Qin, Liu, Dong, Lin
Format Journal Article
LanguageEnglish
Published England 01.01.2016
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Abstract Various rhodium-catalyzed double C–H activations are reviewed. These powerful strategies have been developed to construct C–C bonds, which might be widely embedded in complex aza-fused heterocycles, polycyclic skeletons and heterocyclic scaffolds. In particular, rhodium( iii ) catalysis shows good selectivity and reactivity to functionalize the C–H bond, generating reactive organometallic intermediates in most of the coupling reactions. Generally, intermolecular, intramolecular and multi-component coupling reactions via double C–H activations with or without heteroatom-assisted chelation are discussed in this review.
AbstractList Various rhodium-catalyzed double C-H activations are reviewed. These powerful strategies have been developed to construct C-C bonds, which might be widely embedded in complex aza-fused heterocycles, polycyclic skeletons and heterocyclic scaffolds. In particular, rhodium(iii) catalysis shows good selectivity and reactivity to functionalize the C-H bond, generating reactive organometallic intermediates in most of the coupling reactions. Generally, intermolecular, intramolecular and multi-component coupling reactions via double C-H activations with or without heteroatom-assisted chelation are discussed in this review.
Various rhodium-catalyzed double C–H activations are reviewed. These powerful strategies have been developed to construct C–C bonds, which might be widely embedded in complex aza-fused heterocycles, polycyclic skeletons and heterocyclic scaffolds. In particular, rhodium( iii ) catalysis shows good selectivity and reactivity to functionalize the C–H bond, generating reactive organometallic intermediates in most of the coupling reactions. Generally, intermolecular, intramolecular and multi-component coupling reactions via double C–H activations with or without heteroatom-assisted chelation are discussed in this review.
Author Qin, Liu
Dong, Lin
Li, Shuai-Shuai
Author_xml – sequence: 1
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  surname: Li
  fullname: Li, Shuai-Shuai
  organization: Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China
– sequence: 2
  givenname: Liu
  surname: Qin
  fullname: Qin, Liu
  organization: Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China
– sequence: 3
  givenname: Lin
  surname: Dong
  fullname: Dong, Lin
  organization: Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China
BackLink https://www.ncbi.nlm.nih.gov/pubmed/27099126$$D View this record in MEDLINE/PubMed
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Snippet Various rhodium-catalyzed double C–H activations are reviewed. These powerful strategies have been developed to construct C–C bonds, which might be widely...
Various rhodium-catalyzed double C-H activations are reviewed. These powerful strategies have been developed to construct C-C bonds, which might be widely...
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Title Rhodium-catalyzed C–C coupling reactions via double C–H activation
URI https://www.ncbi.nlm.nih.gov/pubmed/27099126
https://www.proquest.com/docview/1790017823
Volume 14
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