Rhodium-catalyzed C–C coupling reactions via double C–H activation

Various rhodium-catalyzed double C–H activations are reviewed. These powerful strategies have been developed to construct C–C bonds, which might be widely embedded in complex aza-fused heterocycles, polycyclic skeletons and heterocyclic scaffolds. In particular, rhodium( iii ) catalysis shows good s...

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Published inOrganic & biomolecular chemistry Vol. 14; no. 20; pp. 4554 - 4570
Main Authors Li, Shuai-Shuai, Qin, Liu, Dong, Lin
Format Journal Article
LanguageEnglish
Published England 01.01.2016
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Summary:Various rhodium-catalyzed double C–H activations are reviewed. These powerful strategies have been developed to construct C–C bonds, which might be widely embedded in complex aza-fused heterocycles, polycyclic skeletons and heterocyclic scaffolds. In particular, rhodium( iii ) catalysis shows good selectivity and reactivity to functionalize the C–H bond, generating reactive organometallic intermediates in most of the coupling reactions. Generally, intermolecular, intramolecular and multi-component coupling reactions via double C–H activations with or without heteroatom-assisted chelation are discussed in this review.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
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ObjectType-Review-1
ISSN:1477-0520
1477-0539
DOI:10.1039/C6OB00209A