Synthesis of homochiral tris-indanyl molecular rods

Homochiral tris-indanyl molecular rods designed for supramolecular surface self-assembly were synthesized. The chiral indanol moiety was constructed via a Ti-mediated alkyne trimerization. Further manipulations resulted in a homochiral indanol monomer. This was employed as the precursor for successi...

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Published inOrganic & biomolecular chemistry Vol. 12; no. 22; pp. 3679 - 3685
Main Authors Kjeldsen, Niels Due, Funder, Erik Daa, Gothelf, Kurt V.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 14.06.2014
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CHIRAL INDUCTION
SERGEANTS
SEPARATION
EXPRESSION
SURFACES
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Summary:Homochiral tris-indanyl molecular rods designed for supramolecular surface self-assembly were synthesized. The chiral indanol moiety was constructed via a Ti-mediated alkyne trimerization. Further manipulations resulted in a homochiral indanol monomer. This was employed as the precursor for successive Sonogashira and Ohira-Bestman reactions towards the homochiral tris-indanyl molecular rods. The molecular rods will be applied for scanning tunnelling microscopy studies of their surface self-assembly and chirality.
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ISSN:1477-0520
1477-0539
DOI:10.1039/c4ob00011k